Moya Duran Sergio Antonio

Email: 
sergio.moya@usach.cl
Teléfono: 
27 181 066

Abstract

Research is focussed on organometallic chemistry, specifically synthesis, characterization and applications of coordination compounds containing polypyridine and carbonyl ligands. These organometallic compounds are used as catalysts in reactions of industrial or pharmacological interest. Indeed, many compounds have been used as catalysts in the water gas shift reaction, hydrogenation, hydroformilation or in hydroesterification reactions.

 

Línea(s) de investigación: 
Química Inorgánica, Catálisis
Jerarquía: 
Titular
Grados académicos /educación: 
Doctor en Química, Universidad de California, USA, 1981
Profesor de Estado en Química, Universidad de Chile, 1963
Publicaciones: 
  1. S. Zolezzi, S. A. Moya, G. Abarca1, J. Parada, P. Aguirre, “Methoxycarbonylation of olefins catalyzed by Paladium (II) complexes containing naphthyldiphenyl)phosphine ligands”. Applied Organometallic. Chem., (2014), 28(5), 364-37.
  2. B.Aranda, S.Zolezzi, G. Valdebenito, J. Cáceres, S. A, Moya, P. Aguirre “Aminocarbonylation reaction using Palladium(II) complexes containing phosphorous-nitrogen ligands as catalysts” J. Chil. Chem. Soc., 2013, 58, Nº 3. Org. Biomol. Chem., (2014), 12, 979-992.
  3. Sergio A. Moya, Juan Carlos Araya, Juana Gajardo, Véronique Guerchais, Hubert  Le Bozec, Loïc Toupet, Pedro Aguirre. “Synthesis and characteization of ruthenium (II) carbonyl complexes containing naphthyridine and acetylacetonate ligands and their catalytic activity in the hydrogenation transfer reaction” Inorg. Chem. Commun, (2013), 27, 108–110.
  4. S. A. Moya, M Vidal, K. Brown, C. Negrete-Vergara, G. Abarca, P. Aguirre “Ruthenium carbonyl compounds containing polypyridine ligands as catalysts in the reaction of n-benzylideneaniline hydrogenation”. Inorg. Chem. Commun. (2012), 22,146-148.
  5. Ricardo Schmidt, Sergio A. Moya, Pedro Aguirre, Mauricio Fuentealba, Markus Leboschka, Monika Sieger, Mark Niemeyer and Wolfgang Kaim “Synthesis, Characterization and Structure of Tribromo(2-phenyl-1,8-naphthyridine)gold(III)” Z. Naturforsch. (2011), 66b, 677.
  6. S. A. Moya, M. Vidal, G. Abarca, P. Aguirre. “Ruthenium carbonyl compounds containing polypyridine ligands as catalysts in the reaction of N-bencilidenaniline hydrogenation” Catalysis Letters, (2011), 15, 243.
  7. C. Zúñiga, S.A. Moya, . Fuentealba, B. Aranda, P. Aguirre. “Catalytic hydrogenation of N-benzylideneaniline using a new complex of ruthenium (II) derived from 2-ferrocenyl-1,8-naphthyridine” Inorganic Chem. Communications (2011), 14, 964–967.
  8. S. A. Moya, R. Pastene, R. Sartori, C. Díaz, E. Santander, P. Aguirre, A. J. Pardey, C. Longo, P. J. Baricelli. “Synthesis, characterization an preliminary catalytic properties of new copper(I) complexes [CuX(pyrazolyl)2] type” J.of Chil.Chem Soc. (2010), 55(Nº4), 479-482
  9. Juan C. Araya, Juana Gajardo, Sergio A. Moya, Pedro Aguirre, Loic Toupet, J. A. Gareth Williams, Muriel Escadeillas, Hubert, Le Bozec and Veronique Guerchais «, Modulation the Luminescence of an Iridium (III) Complex Incorporating A Di(2-Picoly)Anilino-Appended Bipirydine Ligands with ZN2+ Cations, New J. Chem, (2010),34(1),21-24.
  10. S. A. Moya, M. Vidal, G. Abarca, C. Martinez, V. Guerchais, H. Le Bozec, M. T. Garland, S. Rodriguez, P. Aguirre “ Synthesis, structure and catalytic activities for hydrogen transfer reaction of the carbonyl ruthenium(II) complex containing polypyridine and phosphine ligands.” Inorg.Chem. Commun. (2010), 13(12),1519-1521.
  11. Pablo J. Baricelli, Luis G. Melean, Santiago Ricardes Victor Guanipa, Mariandry Rodriguez, Carlos Romero, Alvaro J. Pardey, Sergio Moya, Merlin Rosales. “ Mo(CO)3(NCMe)(PPh3)2 Synthesis, X-ray structure and evaluation of its catalytic activity for the homogeneous hydrogenation of olefins and their mixtures” J. Organomet. Chem., (2009), 694(21), 3381-3385.
  12. Mauricio Yáñez, Juan Guerrero, Pedro Aguirre, Sergio A. Moya, Gloria Cárdenas-Jirón, “Experimental and Theoretical Characterization of Ru(II) Complexes with Polypyridine and Phosphine Ligands » J. Organomet. Chem. (2009),694(23), 3781-3792.
  13. Cesar Zúñiga, Sergio A. Moya, Pedro Aguirre “ Methoxycarbonylation of Styrene Catalyzed By Palladium Complexes with Ferrocene Derivatives containing Palladium Complexes with Ferrocene Derivatives Containing Nitrogen and Phosphine Ligands,” Catalysis Letters, (2009),130(3-4), 373-379.
Proyectos: 
  • Fondecyt 1120685 Hydrogenatio of Imines Catalyzed by Ruthenium Complexes Containing Phosphine and Polypyridine ligands. Investigador responsable 2012-2015
  • Conicyt – CNRS 836 Proyecto Inorganic Functional Materials Investigador Responsible Universidad de Rennes, Francia, Universidad de Chile, Universidad Católica de Valparaíso y Universidad de Santiago de Chile 2011- 2017
  • Fondecyt 1120149 Carbonylation Reactions Catalyzed by Palladium Complexes Containing Phosphorus – Nitrogen ligands. Potential Application for Synthesis of Pharmaceutical Compounds, Universidad de Chile, Co - investigador 2012-2015
  • Ecos-Conicyt Program . Colaboration Project with Rennes “Nuevas sondas organometálicas luminiscentes para la detección de cationes” University. 2009