Caroli Rezende Marcos
Áreas de investigación:
Química Orgánica
Físico-Química Orgánica
Línea(s) de investigación:
- Solvato- y halo-cromismo: síntesis de nuevas sondas, estudio de sus propiedades y de su comportamiento en solución.
- Interacciones soluto-solvente en solución
- Sistemas micro-heterogéneos y mezclas binarias
- Mecanismos de reacciones orgánicas
Jerarquía:
Titular
Grados académicos /educación:
Estadía post-doctoral, École Normale Supérieure, Paris, Francia, 1985
Doctor en Química (Ph.D.), University of East Anglia, Inglaterra. 1980
Magister en Química (M.Sc.), Universidade Federal de S. Catarina, 1976
Licenciado en Química, Universidad Federal de Rio de Janeiro, 1970
Publicaciones:
Productividad en los últimos cinco años:
30. “Microwave-Promoted Synthesis of 4-Arylpyrimidines by Pd-Catalyzed Suzuki-Miyaura Coupling of 4-Pyrimidyl Tosylates in Water” J.Rodriguez-Aguilar, B. Ordóñez, M.Vidal, M.C.Rezende, M.Domínguez, SynOpen 2017, 1, 24-28.
29. "Theoretical insights into the regioselectivity of a Pictet-Spengler reaction: transition state structures leading to salsolinol and isosalsolinol." Iriux Almodóvar, Marcos Caroli Rezende, Bruce Cassels, Macarena García-Arriagada, J.Phys.Org.Chem. 2017, 30, e3666.
28. “Thermohalochromism of phenolate dyes conjugated with nitro-substituted aryl groups”, L. Hermosilla, M. C. Rezende, V. G. Machado, R. I. Stock, Spectrochim.Acta A, 2017, 173, 556-561.
27. “Aggregation phenomena in photobicyclised pyridinium salts” A. Aracena, M. C. Rezende, M. V. Encinas, C. Vergara and S. O. Vasquez-, New J. Chem., 2017,41, 14589-14594.
26. “Antioxidant-spotting in micelles and emulsions”, C.Aliaga, A.L.deArbina, C. Pastenes , M.C.Rezende, Food Chemistry, 2018, 245, 240-245.
25. “Solvatochromism of conjugated 4-N,N-dimethylaminophenylpyridinium donor-acceptor pairs”, M.Vidal, M.C.Rezende, C. Pastenes, C.Aliaga, M.Domínguez. New J. Chem., 2018, 42, 4223-4231.
24. “Solvatochromic behavior of substituted 4-(nitrostyryl)phenolate dyes in pure solvents and in binary solvent mixtures composed of water and alcohols”, R. I. Stock , C. Sandri , M. C. Rezende, V. G. Machado , J.Mol.Liq. 2018, 264,327-336.
23. “On the Interactions of TEMPO radicals with gold nanoparticles”, C.Aliaga, S. Michea, C. Pastenes, J.Salazar, M.C.Rezende, New J.Chem., 2018, 42, 9764-9770.
22. “Reverse Solvatochromism of Imine Dyes Comprised of 5-Nitrofuran-2-yl or 5-Nitrothiophen-2-yl as Electron Acceptor and Phenolate as Electron Donor”, C.E.A.de Melo, C.R.Nicoleti, M.C.Rezende, A.J.Bortoluzzi, R.S.Heying, R.S.Oliboni, G.F.Caramori, V.G.Machado, Chem.Eur. J. 2018, 24, 9364-9376.
21. “Visualization of phase-transfer catalysis through charge-transfer complexes”, M. C. Rezende, C. Aliaga, G. Barriga, M. Vidal, J.Chem.Ed., 2018, 95 (9), 1631-1635.
20. “The Solvatofluorochromism of 2,4,6-Triarylpyrimidine Derivatives”, J.Rodríguez-Aguilar, M.Vidal, C.Pastenes, M.C.Rezende, C.Aliaga, M.Domínguez, Photochem. Photobiol. 2018, 94, 1100-1108.
19. "Building Pyridinium Molecular Wires as Axial Ligands for Tuning the Electrocatalytic Activity of Iron Phthalocyanines for the Oxygen Reduction Reaction" A. Pizarro, G.A. Anjari, C.Gutiérrez-Cerón, D.Cortés-Arriagada, F. Bernardi, C. Berrios, J. Silva, M.C. Rezende, J. Zagal, R. Oñate, I. Ponce. ACS Catalysis, 2018, 8, 8406-8419.
18. “Influence of the bite natural angle of bidentate biphosphine ligands in the syngas-free branched hydroformylation of b-functionalized olefins”, M. Vilches-Herrera, M.Concha-Puelles, N.Carvajal, J.Molina, R.Santander, M.C.Rezende, S.Luehr, Cat.Comm. 2018, 116, 62-66.
17. “Molecular conductance versus inductive effects of axial ligands on the electrocatalytic activity of self-assembled iron phthalocyanines: The oxygen reduction reaction”, C.Gutiérrez-Ceron, R. Oñate, J.H.Zagal, A. Pizarro, J.F.Silva, C. Castro-Castillo, M.C.Rezende, M.Flores, D. Cortés-Arriagada, A. Toro-Labbé, L.M.Campos, L.Venkataraman, I.Ponce, Electrochim. Acta, 2019, 327, 134996.
16. “The inverted solvatochromism of protonated ferrocenylethenyl-pyrimidines: the first example of the solvatochromic reversal of a hybrid organic/inorganic dye”, M.Vidal, C.Pastenes, M.C.Rezende, C.Aliaga, M.Domínguez Org. Chem. Front., 2019,6, 3896-3901.
15. "Insights into the halochromism of a bithiophene π* probe”, M.Domínguez, R. Mera-Adasme, M.C.Rezende, Spectrochim.Acta A, 2019, 222, 117264.
14. “Interaction of Nitroxide Radicals with an Au8 Nanostructure: Theoretical and Calorimetric Studies”, C.Aliaga, P.Fuentealba, F. Muñoz, C.Pastenes, M.C.Rezende, E.Spodine, C.Cárdenas, J.Phys.Chem.C 2019, 123, 21713-21720.
13. "Solvatofluorochromism of conjugated 4-methoxyphenyl-Pyridinium electron donor-acceptor pairs”, C.Aliaga, M.Vidal, C.Pastenes, M.C.Rezende, M.Domínguez, Dyes and Pigments, 2019, 166, 395-402.
12. "The location of amphiphobic antioxidants in micellar systems: The diving-swan analogy”, A. L. de Arbina, S. Losada-Barreiro, M.C. Rezende, M.Vidal, C. Aliaga, Food Chem. 2019, 279, 288-293.
11. “On the physical-chemical nature of solvent polarizability and dipolarity”, R. Mera-Adasme, M.C. Rezende, M. Domínguez , Spectrochim.Acta A, 2020, 229, 118008.
10. “A comparison of multiparametric methods for the interpretation of solvent-dependent chemical processes”, C.Aliaga, M.Domínguez, P.Rojas, M.C.Rezende, J.Mol.Liquids, 2020, 312, 113362.
9. “Solvatochromism of dyes inspired in Effenberger’s probe”, C.E.A. de Melo, M.Domínguez, M.C.Rezende, V.G.Machado, Dyes and Pigments, 2021,184, 108757.
8. “Preferential solvation index as a tool in the analysis of the behavior of solvatochromic probes in binary solvent mixtures”, Crislaine Sandri, Carlos E.A. de Melo , Luciano A. Giusti , Marcos C. Rezende , Vanderlei G. Machado, J.Mol.Liquids 2021, 328, 115450.
7. “The use of a preferential-solvation index (PSI) for the comparison of halochromic systems”, C.Pastenes, V.G. Machado, M.C.Rezende, J.Mol.Liquids 2021, 334, 115944.
6. “The use of non-ideality parameters for the analysis of thermodynamic properties of binary mixtures “, M.C.Rezende, V.G.Machado,S. Morales, M.Vidal, ACS Omega 2021, 6, 16553-16564.
5. “Applications of a preferential–solvation index (PSI) for the comparison of binary mixtures with ionic liquids”, S. Morales, C. Pastenes, V. G. Machado, M. C. Rezende, J.Mol.Liquids. 2021, 343, 117644.
4. “Alkylated Benzodithienoquinolizinium Salts as Possible Non-Fullerene Organic N -Type Semiconductors: An Experimental and Theoretical Study”, A. Aracena, M. C. Rezende, M. García, K. Muñoz-Becerra,K. Wrighton-Araneda, C. Valdebenito, F. Celis, O. Vásquez, Materials 2021, 14, 6239.
3. “Location, Orientation and Buoyance Effects of Radical Probes as Studied by EPR” C.Aliaga, M.C.Rezende, in Lipid Oxidation in Food and Biological Systems, editor C.Bravo-Díaz, Part II, ps. 133-150, Springer Nature, Switzerland, January 2022.
2. “Binary mixtures with deep eutectic Solvents: Comparing properties with a Non–Ideality approach” V.G.Machado, D. Millán, M.C.Rezende, J.Mol.Liquids. 2022, 359, 119259.
1. “Solvent effects on the wood deligni cation with sustainable solvents “ D.Millán, F. González-Turen, J. Perez-Recabarren , C. Gonzalez-Ponce , M. C. Rezende , A. M. C. Lopes , International Journal of Biological Macromolecules 2022, 211, 490–498.
Proyectos:
(Últimos cinco años)
- Fondecyt 1200192, 2020-2023” Radical probes, antioxidants and fluorescent markers in micro- heterogeneous media”, Investigador alterno
- Fondecyt 1160486, 2016-2019, “Nitroxide-based probes in micro-heterogeneous media: micelles and nanoparticles.”, Investigador alterno.
- Fondecyt 1230004, 2023-2026, “Theoretical studies and applications of chemical processes in binary mixtures of ionic liquids and/or deep eutectic solvents”, Investigador principal
- Fondecyt 1190045, 2019-2022,” Properties and applications of new perichromic probes and theoretical interpretation of their solvatochromism”, Investigador principal
- Fondecyt 1140212, 2014-2017, “Perichromic dyes in homogeneous media and adsorbed on nanoparticles”, Investigador principal
