Domínguez Carú Moisés

Publicaciones

37.- A. Aracena,* M. Domínguez* Molecules 2022, Accepted.“ Computational quantification of the zwitterionic/quinoid ratio of phenolate dyes for their solvatochromic prediction”.

36.- I. Aburto, M. Muñoz, M. Vidal, C. Aliaga, M. Domínguez* J. Mol. Liq. 2022, 368, 120784. “Extending the π-system of inverted solvatochromic phenolate-based dyes shifts their inversion point due to an increment in their sensitivity to solvent polarizability”. https://doi.org/10.1016/j.molliq.2022.120784

35.- R. Mera-Adasme, D. Moraga, R. Medina, M. Domínguez* J. Mol. Liq. 2022, 359, 119302. “Mapping the solute-solvent interactions for the interpretation of the three types of solvatochromism exhibited by phenolate-based dyes”. https://doi.org/10.1016/j.molliq.2022.119302

34.- M. Vidal, J. Rodriguez-Aguilar, I. Aburto, C. Aliaga, M. Domínguez* ChemistrySelect 2021, 6(45), 12858. “Reactivity of 4-pyrimidyl sulfonic esters in Suzuki-Miyaura cross-coupling reactions in water”. https://doi.org/10.1002/slct.202103280

33.- C. E. A. de Melo, M. Domínguez, M. C. Rezende, and V. G. Machado* Dyes and Pigm. 2021, 184, 108757. “Solvatochromism of dyes inspired in Effenberger’s probe”.

https://doi.org/10.1016/j.dyepig.2020.108757

32.- C. Aliaga, M. Domínguez, P. Rojas, M. Rezende* J. Mol. Liq. 2020, 312, 113362. “A comparison of multiparametric methods for the interpretation of solvent-dependent chemical processes”. https://doi.org/10.1016/j.molliq.2020.113362

31.- R. Mera-Adasme, M. C. Rezende, M. Domínguez* Spectrochim. Acta. 2020, 229(15), 118008. “On the physical-chemical nature of solvent polarizability and dipolarity”. https://doi.org/10.1016/j.saa.2019.118008

30.- M. Vidal, C. Pastenes, M. C. Rezende, C. Aliaga, M. Domínguez* Org. Chem. Front. 2019, 6, 3896-3901. “The inverted solvatochromism of protonated ferrocenylethenyl-pyrimidines: the first example of the solvatochromic reversal of a hybrid organic/inorganic dye”. https://doi.org/10.1039/C9QO01043B

29.- M. Domínguez,* R. Mera-Adasme*, M. C. Rezende, Spectrochim. Acta A 2019, 222, 5, 117264. “Insights into the halosolvatochromism of a bithiophene π* probe”.

https://doi.org/10.1016/j.saa.2019.117264

28.- R. Mera-Adasme*, M. Domínguez,* O. Denis-Alpizar J. Mol. Mod. 2019, 25:176. “A benchmark for the size of the QM system required for accurate hybrid QMMM calculations on the metal site of the protein copper, zinc superoxide dismutase”. https://doi.org/10.1007/s00894-019-4066-8

27.- C. Aliaga, M. Vidal, C. Pastenes, M. C. Rezende*, M. Domínguez* Dyes Pigm. 2019, 166, 395-402. “Solvatofluorochromism of Conjugated 4-Methoxyphenyl-Pyridinium Electron Donor-Acceptor Pairs”. https://doi.org/10.1016/j.dyepig.2019.03.054

26.- J. Rodríguez-Aguilar, M. Vidal, C. Pastenes, C. Aliaga,* M. C. Rezende and M. Domínguez* Photochem. Photobiol. 2018, 94(6), 1100-1108. “The Solvatofluorochromism of 2,4,6-Triarylpyrimidine Derivatives”. bhttps://doi.org/10.1111/php.12982

25.- R. Mera-Adasme*, M. Domínguez* Phys. Chem. Chem. Phys. 2018, 20, 18127-18132. “A computationally-derived model for the solvatochromism of p-phenolates with high predictive power”. https://doi.org/10.1039/C8CP02424C

24.- M. Vidal, M. C. Rezende,* C. Pastene, C. Aliaga, M. Domínguez* New J. Chem. 2018, 42, 4223-4231. “Solvatochromism of conjugated 4-N,N-dimethylaminophenyl-pyridinium donor-acceptor pairs”. https://doi.org/10.1039/C7NJ04992G

23.- J. Rodríguez-Aguilar, B. Ordóñez, Matías Vidal, M. C. Rezende, M. Domínguez* SynOpen 2017, 01(01): 0024-0028. “Microwave-promoted Synthesis of 4-Arylpyrimidines by Pd-Catalyzed Suzuki-Miyaura Coupling of 4-Pyrimidyl Tosylates in Water”. https://doi.org/10.1055/s-0036-1588810

22.- H. –U. Reissig, M. Domínguez* ChemistrySelect 2016, 16, 5270–5275. “N-Methylpyridinium-4-phenolates: Generation of a Betaine Dye Library Bearing Different Spacer Units and Their Solvatochromism”. https://doi.org/10.1002/slct.201601148

21.- M. Domínguez,* M. C. Rezende J. Mol. Mod. 2016, 22, 218. “A Monte Carlo-Quantum Mechanics Study of a Solvatochromic π* Probe”. https://doi.org/10.1007/s00894-016-3083-0

20.- M. Vidal, M. García-Arriagada, M. C. Rezende, M. Domínguez* Synthesis, 2016, 48(23), 4246-4252. “Ultrasound-promoted Synthesis of 4-Pyrimidinols and their Tosyl Derivatives”. https://doi.org/10.1055/s-0035-1562788

19.- M. Domínguez, V. G. Machado, L. Nandi, M. C. Rezende,* P. Silva J. Chem. Kin. 2015, 47(12), 803. “A Kinetic Investigation of Regioselective Solvation of a

Solvatochromic Dye in Aqueous Alcohols”. https://doi.org/10.1002/kin.20963

18.- M. C. Rezende,* M. Domínguez M. J. Mol. Mod. 2015, 21, 212. “The solvatochromism of phenolate betaines: comparing different cavities of a polarized continuum model”. https://doi.org/10.1007/s00894-015-2769-z

17.- C. E. A. de Melo, L. G. Nandi, M. Domínguez, M. C. Rezende, V. G. Machado* J. Phys. Org. Chem. 2015, 28, 250. “Solvatochromic behavior of dyes with

dimethylamino electron-donor and nitro electron-acceptor groups in their molecular structure”. https://doi.org/10.1002/poc.3402

16.- M. Jasinsky,* M. Grzegorz,* M. Storlaski, W. Costa, M. Domínguez, H. –U. Reissig* Chem. Asian J. 2014, 9(9), 2641-2648. “Reactions of cycloaliphatic thioketones and their oxo analogues with lithiated methoxyallene: a new approach to vinylthiiranes”. https://doi.org/10.1002/asia.201402547

15.- M. Domínguez, H. –U. Reissig* ChemInform 2014, 45(42), 167. https://doi.org/10.1002/chin.201442167

14.- M. Domínguez, H. –U. Reissig* Synthesis 2014, 46(08), 1100.  “New 4-Pyridyl Nonaflates as Precursors for Push-Pull Solvatochromic Dyes”. https://doi.org/10.1055/s-0033-1340839

13.- M. K. Bera, P. Hommes, M. Domínguez, H. –U. Reissig* Beilstein J. Org. Chem. 2014, 10, 394. “The Flögel-three-component reaction with dicarboxylic acids – an approach to bis(β-alkoxy-β-ketoenamides) for the synthesis of complex pyridine and pyrimidine derivatives”. https://doi.org/10.3762/bjoc.10.37

12.- M. Domínguez,* M. C. Rezende, S. Márquez J. Mol. Mod. 2013, 19(2), 689. “Theoretical study of the solvatochromism of a donor-acceptor bithiophene”. https://doi.org/10.1007/s00894-012-1593-y

11.- M. C. Rezende,* M. Domínguez, A. Aracena Spectrochim. Acta Part A 2012, 87, 61. “The positive halochromism of phenolate dyes in hydroxylic solutions of tetraalkylammonium cations”. https://doi.org/10.1016/j.saa.2011.11.010

10.- M. C. Rezende,* M. Domínguez, A. Aracena, D. Millán Chem. Phys. Lett. 2011, 514, 267. “Solvatochromism and electrophilicity”. https://doi.org/10.1016/j.cplett.2011.08.070

9.- M. Domínguez, M. C. Rezende* J. Phys. Org. Chem. 2010, 23(2), 156. “Towards a unified view of the solvatochromism of phenolate betaine dyes”. https://doi.org/10.1002/poc.1599

8.- M. Domínguez, M. C. Rezende* J. Iran. Chem. Soc. 2010, 7(4), 995. “The Cationic Halochromism of Phenolate Betaines: Molecular Dynamics and Quantum Mechanics Studies”. https://doi.org/10.1007/BF03246096

7.- M. C. Rezende,* R. Oñate, G. Núñez, M. Domínguez, C. Mascayano Dyes Pigments 2009, 83(3), 391. “Lipophilic contributions to the solvatochromism of analogous betaines”. https://doi.org/10.1016/j.dyepig.2009.06.011

6.- M. C. Rezende,* R. Oñate, M. Domínguez, D. Millán Spec. Lett. 2009, 42(2), 81. “Solvatochromism and Halochromism of N-(4-Oxyphenyl)-5-nitro-2-thiophenecarboxaldimine”. https://doi.org/10.1080/00387010802428617

5.- D. Millán, M. Domínguez, M. C. Rezende Dyes Pigments 2008, 77(2), 441. “Solvatochromic hydrazone anions derived from chalcones”. https://doi.org/10.1016/j.dyepig.2007.07.011

4.- M. C. Rezende, F. Jara, M. Domínguez Tetrahedron 2006, 62(33), 7817. “The interaction of solvatochromic pyridiniophenolates with cyclodextrins”. https://doi.org/10.1016/j.tet.2006.05.053

3.- M. C. Rezende,* F. Jara, M. Domínguez J. Chem. Edu. 2006, 83(6), 937. “Evaluating the Internal Charge-Transfer in Benzylidene Derivatives of N,N'-Dimethylbarbituric Acid”. https://doi.org/10.1021/ed083p937

2.- F. Jara, M. Domínguez, M. C. Rezende, E. R. Tiekink, J. L. Wardell, S. M. Wardell* Acta Crytallographica 2006, E62(01), 3495. “3-Benzyl-2,4,6-triphenylpyrylium

tetrafluoroborate”. https://doi.org/10.1107/S1600536806028285

1.- M.C. Rezende, M. Domínguez, J. L. Wardell, J. M. Skakle, J. N. Low, C. Glidewell* Acta Crystallographica 2005, C61(5), 306. “Supramolecular structures of five 5-

(arylmethylene)-1,3-dimethylpyrimidine-2,4,6- (1H,3H,5H)-triones: isolated molecules, hydrogen-bonded chains and chains of fused hydrogen-bonded rings”.

https://doi.org/10.1107/S0108270105008498

Proyectos

2014-2017: Fondecyt de iniciación Nº 11140497 “Intramolecular cyclization of 3,5-diketoenamines and 3,5- diketoenamides as flexible precursors for the preparations of novel azaheterocyclic compounds”, Investigador responsable.

2020-2024: Fondecyt regular Nº 1200116 “Toward a general model for the inverted solvatochromism of light-emitting and non-light-emitting sensors: A synthetic and computational study”, Investigador responsable.

2020-2024: Fondecyt regular No 1200200 “A theoretical study of the dynamical relationship between structural elements of the protein copper, zinc superoxide dismutase implicated in the pathogenesis of amyotrophic lateral sclerosis”, Co-Investigador.

2020-2024: Fondecyt regular No 1200192 “Radical probes, antioxidants and fluorescent markers in micro-heterogeneous media”, Co-Investigador.

2019-2023: Fondecyt regular N° 1190045 “Properties and applications of new perichromic probes and theoretical interpretation of their solvatochromism”, Co-Investigador.

Otros

1. Tesis dirigidas en los últimos 10 años

a. Tesis de pregrado: 7 finalizadas

b. Tesis de magister: 2 finalizadas y 2 en desarrollo

c. Tesis de doctorado: 2 en desarrollo
2. Coordinador del grupo del comité de Química, Biología y Medicina, Dirección de Investigación

Científica y Tecnológica (DICYT), Universidad de Santiago de Chile. (2022-)

3. Referee en revistas internacionales:

a. Industrial & Engineering Chemistry Research

b. Journal of Molecular Modeling

c. Analytical Letters

d. Journal of Molecular Modeling

e. Arabian Journal of Chemistry

f. Journal of Molecular Structure

g. Dyes and Pigments

h. Current Topics in Medicinal Chemistry

i. CARBON

j. Journal of Physical Organic Chemistry

k. Synthesis

l. Journal of Molecular Liquids

m. European Journal of Organic Chemistry

n. Talanta

o. New Journal of Chemistry

4. Miembro de la Comisión Estratégica de Sostenibilidad USACH (2021-)

5. Miembro del Comité de innovación curricular de química y farmacia, USACH (2020-)